张庄铁矿高阶段矿房切割天井施工工艺试验

张庄铁矿设计采矿方法为大直径深孔阶段空场嗣后充填法。为了最大化发挥采矿设备性能，降低采切工程量，提高回采效率，通过实施一系列技术攻关，实现了将采矿阶段高度由原来的60 m提高到90 m。而作为最初爆破回采的自由面及爆破补偿空间，切割天井施工工艺为影响高阶段矿房爆破回采效果的关键因素，施工质量的优劣，直接影响矿房爆破回采生产作业能否顺利进行，而二次处理在增加施工成本的同时将带来安全隐患。张庄铁矿在面临可参考的成熟经验较少的情况下，结合现场可用的作业条件采取了对比试验的方法，在安全、技术及经济多方面综合分析比较下，确定了最终方案，为张庄铁矿安全稳定生产奠定了基础，同时研究成果可为大型地下矿山生产实践提供一定的参考。     

矿山深部开采岩体稳定性监测技术研究

针对矿山深部开采过程中易发生地压动力灾害的问题，基于微震监测技术，结合矿山实际特点建立岩体稳定性监测系统。优化台网设计，通过定点爆破的方法进行波速校正，最终建立了定位误差在10m,灵敏度在-2.2的监测台网。对监测数据进行波形拾取，分析微震事件时空演化特征，圈定潜在危险区域，并对潜在危险区域围岩变形损伤进行分析。最终总结出微震事件大幅度上升且处于较高水平、空间分布高度集聚、能量指数突然下降而累计视体积迅速上升的动力灾害预警前兆。研究结果可为深部开采岩体稳定性监测提供参考。     

The Effect of Noble-Metal Deposition Routes on the Characteristics and Photocatalytic Activity of M-TiBi1.9%O2 (M = Pt and Pd)

Topics in Catalysis - The effect of deposited noble-metals and their deposition routes on the photocatalytic decomposition of organic pollutants over M-TiBi1.9%O2 (M?=?Pt and Pd) under...     

12CrNi3钢外锁止套局部表面激光淬火工艺

利用半导体激光宽带对12CrNi3外锁止套局部进行表面淬火处理,并对处理后的零件进行外观检验、显微组织观察、硬度检测分析和摩擦磨损试验。试验结果表明:采取定光斑方式,激光头到工件表面扫描区域中心点距离375 mm(离焦量为0),工件倾斜22°,激光头倾斜18°,温度1350 ℃,扫描速度9 mm/s,单道扫描后表面平整性最好。表面激光淬火硬化层为750～1000 μm,最浅处为443.1 μm,硬化区组织为极细小马氏体组织,硬度达600～700 HV0.2,是基体硬度的2倍左右, 约为渗碳+淬火态硬度的1.3倍,且相变硬化区耐磨性能明显提高。     

Metal-organic framework-based CO2 capture: from precise material design to high-efficiency membranes

A low-carbon economy calls for CO₂ capture technologies. Membrane separations represent an energy-efficient and environment-friendly process compared with distillations and solvent absorptions. Metal-organic frameworks (MOFs), as a novel type of porous materials, are being generated at a rapid and growing pace, which provide more opportunities for high-efficiency CO₂ capture. In this review, we illustrate a conceptional framework from material design and membrane separation application for CO₂ capture, and emphasize two importance themes, namely (i) design and modification of CO₂-philic MOF materials that targets secondary building units, pore structure, topology and hybridization and (ii) construction of crack-free membranes through chemical epitaxy growth of active building blocks, interfacial assembly, ultrathin two-dimensional nanosheet assembly and mixed-matrix integration strategies, which would give rise to the most promising membrane performances for CO₂ capture, and be expected to overcome the bottleneck of permeability-selectivity limitations.     

S6-11综放工作面回风巷支护设计优化

针对常村矿回采巷道变形严重,影响正常生产的问题,通过对矿井赋存条件、巷道现有支护形式和围岩变形过程分析,采用新型联合支护技术对S6-11回风巷道支护进行优化。现场实测巷道顶底板相对移近量最大120mm,两帮相对移近量最大140mm,均在允许正常范围之内。     

基于BEPCⅡ数字束流位置测量系统电子学系统的设计与实现

BEPCⅡ加速器的束流位置测量系统（BPM）模拟电子学经过十余年的运行逐渐老化，故障率上升，亟需进行升级改造。本文根据该需求，自行设计了基于BEPCⅡ系统参数的数字BPM电子学系统，内容包括模拟信号处理电子学、数字信号处理电子学、BPM固件算法逻辑、数据获取软件以及系统测试等多个部分。设计的数字BPM电子学系统经实验板级性能测试、实验室系统测试以及在线束流测试，结果表明该系统能满足BEPCⅡ装置对束流位置测量的需求。     

齐大山铁矿南帮含水构造带探测研究

为解决采空区突发涌水给矿山安全生产带来的安全威胁,以齐大山铁矿为研究对象,以高密度电阻率法含水构造带理论模型的正演模拟研究为基础,运用高密度电阻率法对采场南帮含水构造带的异常范围进行了圈定;运用瞬变电磁法进行了二次探测,并对高密度电阻率法所圈定的异常范围进行了验证。研究表明:含水构造带显示为低阻异常特征,在高密度电阻率法探测成果图中显示的两处低阻异常与含水构造带理论模型的正演模拟结果一致;同时,在瞬变电磁法探测成果图中显示的低阻区域均在高密度电阻率法所圈定的低阻异常范围内,二者相互验证,这两处低阻异常均为含水构造带的地球物理异常特征的显示,表明采用高密度电阻率法和瞬变电磁法组合识别技术可实现对隐伏含水构造带的先导性探测。     

Headspace fingerprinting approach to identify the major pathway influencing volatile patterns of vinasse-cured duck processed by high pressure,as well as its impact on physicochemical and sensory attributes

As a decisive attribute, flavour could be influenced by HP treatments through multiple physical and chemical pathways within the high pressure (HP)-assisted meat curing process. This investigation aimed to identify the major pathway influencing volatile flavour patterns of two representative vinasse-cured duck (VCD) products with HP treatments (150–300 MPa/15 min), including wet and dry types, by employing headspace fingerprinting as an untargeted approach. Results suggested that HP treatments greatly lowered moisture contents and increased Warner-Bratzler shear force and thiobarbituric acid reactive substances of the cured samples. According to multivariate models, the volatile flavour patterns of the HP-processed VCD could be clearly separated from the unprocessed samples, but the VCD pressurised at different intensities represented similar volatile fingerprinting, which was validated by e-nose analysis. The discriminant analysis (OPLS-DA) model outlined vinasse-derived ethanol, acetic acid, 3-methyl-1-butanol, 2-methyl-1-butanol, phenethyl alcohol and 2-methyl-3-octanone as the major discriminant aromas across the unpressurised and pressurised samples.     

Facile preparation of highly dispersed Pt nanoparticles supported on heteroatom-containing porous carbon nanospheres and their catalytic properties for the reduction of 4-nitrophenol

Heteroatom-containing porous carbon nanospheres with a high surface area were firstly fabricated by pyrolysis of poly(cyclotriphosphazene-co-4,4′-sulfonyldiphenol) (PZS) nanospheres which were fabricated by a facile polycondensation between hexachlorocyclotriphosphazene and 4,4′-sulfonydiphenol. Then the porous carbon nanosphere-supported Pt nanoparticles (Pt NPs@C-PZS) were synthesized by a simple microwave reduction method, during which Pt NPs were highly dispersed on the surface of carbon supports. The surface morphologies and chemical composition of the as-obtained C-PZS and Pt NPs@C-PZS nanocomposites were characterized by SEM, TEM, XRD, XPS, and Raman spectroscopy. Characterization results showed that the Pt NPs with an average diameter of 2 nm was well anchored onto the surface of C-PZS nanospheres. In addition, the as-prepared Pt NPs@C-PZS nanocomposites exhibited an excellent catalytic capability towards the reduction of 4-nitrophenol to 4-aminophenol by excessive sodium borohydride (NaBH₄) at room temperature.